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White chocolate in fragrances generally presents as a sweet, creamy, and indulgent scent, often with buttery and vanilla-like notes. It's a popular choice in gourmand perfumes, those designed to evoke food-like scents, due to its ability to add a creamy, comforting, and almost edible quality. Sometimes, it's paired with other notes like coffee, cinnamon, or even exotic peppers to balance the sweetness and add complexity.